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Pressure induced polymerization of acetylide anions in CaC2 and 107 fold enhancement of electrical conductivity (2016)
Journal Article
Zheng, H., Wang, L., Li, K., Yang, Y., Wang, Y., Wu, J., …Jin, C. (2017). Pressure induced polymerization of acetylide anions in CaC2 and 107 fold enhancement of electrical conductivity. Chemical Science, 8(1), 298-304. https://doi.org/10.1039/c6sc02830f

Transformation between different types of carbon–carbon bonding in carbides often results in a dramatic change of physical and chemical properties. Under external pressure, unsaturated carbon atoms form new covalent bonds regardless of the electrosta... Read More about Pressure induced polymerization of acetylide anions in CaC2 and 107 fold enhancement of electrical conductivity.