An unexpected TTFAQ donor-fluorene acceptor reaction resulting in a novel salt: 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylium)-anthracene bis(2,5,7-trinitro-4-bromo-9-cyanofluorenide) dioxane trisolvate

Batsanov, A.S.; Bryce, M.R.; Lyubchik, S.B.; Perepichka, I.F.

Abstract

Reaction of the electron acceptor 2,5,7-trinitro-4-bromo-9-dicyanomethylenefluorene (1) and the electron donor 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylidene)-9,10- dihydroanthracene (2) in dioxane resulted in the formation of a novel type of salt with the previously unknown 2,5,7-trinitro-4-bromo-9-cyanofluorenide anion (3(-)): (2)(2+).(3)(2).3C(4)H(8)O(2).

• Journal Article Type: Article
• Publication Date: 2002-10
• Journal: Acta crystallographica. Section B, Structural science.
• Print ISSN: 0108-7681
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 58
• Pages: O1106-O1110
• Public URL: https://durham-repository.worktribe.com/output/1571556