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An unexpected TTFAQ donor-fluorene acceptor reaction resulting in a novel salt: 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylium)-anthracene bis(2,5,7-trinitro-4-bromo-9-cyanofluorenide) dioxane trisolvate

Batsanov, A.S.; Bryce, M.R.; Lyubchik, S.B.; Perepichka, I.F.

Authors

A.S. Batsanov

S.B. Lyubchik

I.F. Perepichka



Abstract

Reaction of the electron acceptor 2,5,7-trinitro-4-bromo-9-dicyanomethylenefluorene (1) and the electron donor 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylidene)-9,10- dihydroanthracene (2) in dioxane resulted in the formation of a novel type of salt with the previously unknown 2,5,7-trinitro-4-bromo-9-cyanofluorenide anion (3(-)): (2)(2+).(3)(2).3C(4)H(8)O(2).

Citation

Batsanov, A., Bryce, M., Lyubchik, S., & Perepichka, I. (2002). An unexpected TTFAQ donor-fluorene acceptor reaction resulting in a novel salt: 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylium)-anthracene bis(2,5,7-trinitro-4-bromo-9-cyanofluorenide) dioxane trisolvate. Acta crystallographica. Section B, Structural science, 58, O1106-O1110

Journal Article Type Article
Publication Date 2002-10
Journal Acta crystallographica. Section B, Structural science.
Print ISSN 0108-7681
Publisher Wiley
Peer Reviewed Peer Reviewed
Volume 58
Pages O1106-O1110