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High-Mobility and High-Optical Quality Atomically Thin WS 2

Reale, Francesco; Palczynski, Pawel; Amit, Iddo; Jones, Gareth F; Mehew, Jake D; Bacon, Agnes; Ni, Na; Sherrell, Peter C; Agnoli, Stefano; Craciun, Monica F; others

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Authors

Francesco Reale

Pawel Palczynski

Gareth F Jones

Jake D Mehew

Agnes Bacon

Na Ni

Peter C Sherrell

Stefano Agnoli

Monica F Craciun

others



Abstract

The rise of atomically thin materials has the potential to enable a paradigm shift in modern technologies by introducing multi-functional materials in the semiconductor industry. To date the growth of high quality atomically thin semiconductors (e.g. WS2) is one of the most pressing challenges to unleash the potential of these materials and the growth of mono- or bi-layers with high crystal quality is yet to see its full realization. Here, we show that the novel use of molecular precursors in the controlled synthesis of mono- and bi-layer WS2 leads to superior material quality compared to the widely used direct sulfidization of WO3-based precursors. Record high room temperature charge carrier mobility up to 52 cm2/Vs and ultra-sharp photoluminescence linewidth of just 36 meV over submillimeter areas demonstrate that the quality of this material supersedes also that of naturally occurring materials. By exploiting surface diffusion kinetics of W and S species adsorbed onto a substrate, a deterministic layer thickness control has also been achieved promoting the design of scalable synthesis routes.

Citation

Reale, F., Palczynski, P., Amit, I., Jones, G. F., Mehew, J. D., Bacon, A., …others. (2017). High-Mobility and High-Optical Quality Atomically Thin WS 2. Scientific Reports, 7(1), Article 14911. https://doi.org/10.1038/s41598-017-14928-2

Journal Article Type Article
Acceptance Date Oct 19, 2017
Online Publication Date Nov 2, 2017
Publication Date Nov 2, 2017
Deposit Date Jul 5, 2018
Publicly Available Date Jul 6, 2018
Journal Scientific Reports
Publisher Nature Research
Peer Reviewed Peer Reviewed
Volume 7
Issue 1
Article Number 14911
DOI https://doi.org/10.1038/s41598-017-14928-2
Public URL https://durham-repository.worktribe.com/output/1322202

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Publisher Licence URL
http://creativecommons.org/licenses/by/4.0/

Copyright Statement
This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.






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