Chlorophyll Triggered One-Pot Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones via Photo Induced Electron transfer reaction
Harsh, Simran; Kumar, Sanjay; Sharma, Rohit; Kumar, Yogesh; Kumar, Rupesh
The photocatalytic potential of chlorophyll has been investigated for the facile synthesis of dihydropyrimidinones utilizing concentrated solar irradiation towards sustainable energy solutions. This, one-pot, multicomponent Biginelli reaction, which involves a photoinduced electron transfer (PET) mechanism, affords a green and efficient approach for the transformation of the commercial aldehydes, β-keto ester and urea into valuable 3,4-dihydropyrimidin-2(1H)-ones with wide substrate scope and diversity. These improved reaction conditions allow the formation of a variety of substituted dihydropyrimidinones with high yields and purity in a short duration of time and mild reaction conditions.
Harsh, S., Kumar, S., Sharma, R., Kumar, Y., & Kumar, R. (2020). Chlorophyll Triggered One-Pot Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones via Photo Induced Electron transfer reaction. Arabian Journal of Chemistry, 13(3), 4720-4730. https://doi.org/10.1016/j.arabjc.2019.11.002
|Journal Article Type||Article|
|Acceptance Date||Nov 10, 2019|
|Online Publication Date||Nov 22, 2019|
|Deposit Date||Nov 22, 2019|
|Publicly Available Date||Jul 5, 2020|
|Journal||Arabian Journal of Chemistry|
|Peer Reviewed||Peer Reviewed|
Published Journal Article
Publisher Licence URL
© 2019 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).