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Sulfonyl-Substituted Heteroleptic Cyclometalated Iridium(III) Complexes as Blue Emitters for Solution-Processable Phosphorescent Organic Light-Emitting Diodes (2016)
Journal Article
Benjamin, H., Zheng, Y., Batsanov, A., Fox, M., Al-Attar, H., Monkman, A., & Bryce, M. (2016). Sulfonyl-Substituted Heteroleptic Cyclometalated Iridium(III) Complexes as Blue Emitters for Solution-Processable Phosphorescent Organic Light-Emitting Diodes. Inorganic Chemistry, 55(17), 8612-8627. https://doi.org/10.1021/acs.inorgchem.6b01179

The synthesis is reported of a series of blue-emitting heteroleptic iridium complexes with phenylpyridine (ppy) ligands substituted with sulfonyl, fluorine, and/or methoxy substituents on the phenyl ring and a picolinate (pic) ancillary ligand. Some... Read More about Sulfonyl-Substituted Heteroleptic Cyclometalated Iridium(III) Complexes as Blue Emitters for Solution-Processable Phosphorescent Organic Light-Emitting Diodes.

The Role of Local Triplet Excited States and D-A Relative Orientation in Thermally Activated Delayed Fluorescence: Photophysics and Devices (2016)
Journal Article
Dias, F., Santos, J., Graves, D., Data, P., Nobuyasu, R., Fox, M., …Monkman, A. (2016). The Role of Local Triplet Excited States and D-A Relative Orientation in Thermally Activated Delayed Fluorescence: Photophysics and Devices. Advanced Science, 3(12), Article 1600080. https://doi.org/10.1002/advs.201600080

Here, a comprehensive photophysical investigation of a the emitter molecule DPTZ-DBTO2, showing thermally activated delayed fluorescence (TADF), with near-orthogonal electron donor (D) and acceptor (A) units is reported. It is shown that DPTZ-DBTO2 h... Read More about The Role of Local Triplet Excited States and D-A Relative Orientation in Thermally Activated Delayed Fluorescence: Photophysics and Devices.