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Vanadium isotope fractionation during plutonic differentiation and implications for the isotopic composition of the upper continental crust (2024)
Journal Article
Stow, M. A., Prytulak, J., Humphreys, M. C., Hammond, S. J., & Nowell, G. M. (2024). Vanadium isotope fractionation during plutonic differentiation and implications for the isotopic composition of the upper continental crust. Earth and Planetary Science Letters, 643, Article 118825. https://doi.org/10.1016/j.epsl.2024.118825

The analysis of emerging stable isotopic systems in clastic sedimentary rocks is increasingly used to determine the average composition of the upper continental crust through geological time. Any temporal variations can then be linked to global-scale... Read More about Vanadium isotope fractionation during plutonic differentiation and implications for the isotopic composition of the upper continental crust.

Rhenium elemental and isotopic variations at magmatic temperatures (2024)
Journal Article
Wang, W., Dickson, A., Stow, M., Dellinger, M., Burton, K., Savage, P., …Prytulak, J. (2024). Rhenium elemental and isotopic variations at magmatic temperatures. Geochemical perspectives letters, 28, 48-53. https://doi.org/10.7185/geochemlet.2402

Recent analytical advances in the measurement of rhenium (Re) isotope ratios allow its potential as a palaeoredox and chemical weathering proxy to be explored. However, a successful isotopic proxy must be grounded by an understanding of its compositi... Read More about Rhenium elemental and isotopic variations at magmatic temperatures.

No V-Fe-Zn isotopic variation in basalts from the 2021 Fagradalsfjall eruption (2023)
Journal Article
Stow, M., Prytulak, J., Burton, K., Nowell, G., Marshall, E., Halldórsson, S., …Caracciolo, A. (2023). No V-Fe-Zn isotopic variation in basalts from the 2021 Fagradalsfjall eruption. Geochemical perspectives letters, 27, 54-58. https://doi.org/10.7185/geochemlet.2335

The Earth’s mantle is chemically heterogeneous in space and time, which is often reflected by variable isotopic compositions of mantle derived basalts. Basalts from the first 40 days of the 2021 Fagradalsfjall eruption, Reykjanes Peninsula, Iceland,... Read More about No V-Fe-Zn isotopic variation in basalts from the 2021 Fagradalsfjall eruption.

Equilibrium partitioning and isotopic fractionation of nitrogen between biotite, plagioclase, and K-feldspar during magmatic differentiation (2023)
Journal Article
Boocock, T. J., Stüeken, E. E., Bybee, G. M., König, R., Boyce, A. J., Prytulak, J., …Mikhail, S. (2023). Equilibrium partitioning and isotopic fractionation of nitrogen between biotite, plagioclase, and K-feldspar during magmatic differentiation. Geochimica et Cosmochimica Acta, 356, 116-128. https://doi.org/10.1016/j.gca.2023.07.010

A significant portion of the continental crust is composed of plutonic igneous rocks. However, little is known
about the geochemical behaviour of N between the different minerals during magmatic differentiation. To
provide new constraints for the... Read More about Equilibrium partitioning and isotopic fractionation of nitrogen between biotite, plagioclase, and K-feldspar during magmatic differentiation.

A primary magmatic source of nitrogen to Earth’s crust (2023)
Journal Article
Boocock, T. J., Mikhail, S., Boyce, A. J., Prytulak, J., Savage, P. S., & Stüeken, E. E. (2023). A primary magmatic source of nitrogen to Earth’s crust. Nature Geoscience, https://doi.org/10.1038/s41561-023-01194-3

The igneous portion of Earth’s continental crust represents a long-term sink of terrestrial nitrogen, but the origin of the nitrogen in this reservoir remains ambiguous. Possible sources include magmatic differentiation of mantle-derived melts (that... Read More about A primary magmatic source of nitrogen to Earth’s crust.

Slab to back-arc to arc: Fluid and melt pathways through the mantle wedge beneath the Lesser Antilles (2023)
Journal Article
Hicks, S. P., Bie, L., Rychert, C. A., Harmon, N., Goes, S., Rietbrock, A., …Kendall, J. (2023). Slab to back-arc to arc: Fluid and melt pathways through the mantle wedge beneath the Lesser Antilles. Science Advances, 9(5), https://doi.org/10.1126/sciadv.add2143

Volatiles expelled from subducted plates promote melting of the overlying warm mantle, feeding arc volcanism. However, debates continue over the factors controlling melt generation and transport, and how these determine the placement of volcanoes. To... Read More about Slab to back-arc to arc: Fluid and melt pathways through the mantle wedge beneath the Lesser Antilles.

Identifying Tethys oceanic fingerprint in post-collisional potassium-rich lavas in Tibet using thallium isotopes (2022)
Journal Article
Wei, F., Prytulak, J., Baker, E. B., Xu, J., & Zhao, B. (2022). Identifying Tethys oceanic fingerprint in post-collisional potassium-rich lavas in Tibet using thallium isotopes. Chemical Geology, 607, Article 121013. https://doi.org/10.1016/j.chemgeo.2022.121013

Following the Indian-Asian continental collision, the Tibetan Plateau experienced continuous magmatism from south to north, most of which is characterized by high potassium (K) content and negative niobium‑tantalum‑titanium (Nb-Ta-Ti) anomalies. We p... Read More about Identifying Tethys oceanic fingerprint in post-collisional potassium-rich lavas in Tibet using thallium isotopes.

Magma recharge patterns control eruption styles and magnitudes at Popocatépetl volcano (Mexico) (2022)
Journal Article
Mangler, M. F., Petrone, C. M., & Prytulak, J. (2022). Magma recharge patterns control eruption styles and magnitudes at Popocatépetl volcano (Mexico). Geology, 50(3), 366-370. https://doi.org/10.1130/g49365.1

Diffusion chronometry has produced petrological evidence that magma recharge in mafic to intermediate systems can trigger volcanic eruptions within weeks to months. However, less is known about longer-term recharge frequencies and durations priming m... Read More about Magma recharge patterns control eruption styles and magnitudes at Popocatépetl volcano (Mexico).

Integrated Petrological and Fe-Zn Isotopic Modelling of Plutonic Differentiation (2021)
Journal Article
Stow, M. A., Prytulak, J., Humphreys, M. C., & Nowell, G. M. (2022). Integrated Petrological and Fe-Zn Isotopic Modelling of Plutonic Differentiation. Geochimica et Cosmochimica Acta, 320, 366-391. https://doi.org/10.1016/j.gca.2021.12.018

The upper continental crust is formed from chemically diverse granitic plutons. Active debate surrounds the range of physical conditions (P-T-X-fO2) and differentiation processes which occur in mush bodies that solidify to form plutons. Transition me... Read More about Integrated Petrological and Fe-Zn Isotopic Modelling of Plutonic Differentiation.

Thallium Isotopic Compositions in Hawaiian Lavas: Evidence for Recycled Materials on the Kea Side of the Hawaiian Mantle Plume (2021)
Journal Article
Williamson, N. M., Weis, D., & Prytulak, J. (2021). Thallium Isotopic Compositions in Hawaiian Lavas: Evidence for Recycled Materials on the Kea Side of the Hawaiian Mantle Plume. Geochemistry, Geophysics, Geosystems, 22(9), Article e2021GC009765. https://doi.org/10.1029/2021gc009765

Hawaiian volcanoes record 6 Ma of potentially deep mantle chemistry and form two parallel volcanic chains that are geochemically unique, named Loa and Kea. Loa volcanoes erupt lavas with isotopically enriched compositions thought to reflect the prese... Read More about Thallium Isotopic Compositions in Hawaiian Lavas: Evidence for Recycled Materials on the Kea Side of the Hawaiian Mantle Plume.