Outputs (6)

The electronic structures of diruthenium complexes containing an oligo(phenylene ethynylene) bridging ligand, and some related molecular structures (2010)
Journal Article
Khairul, W. M., Fox, M. A., Schauer, P. A., Yufit, D. S., Albesa-Jové, D., Howard, J. A., & Low, P. J. (2010). The electronic structures of diruthenium complexes containing an oligo(phenylene ethynylene) bridging ligand, and some related molecular structures. Dalton Transactions, 39(48), 11605-11615. https://doi.org/10.1039/c0dt00809e

The complexes [{Cp′(L2)Ru}CCC6H4CCC6H2(OMe)2CCC6H4CC{Ru(L2)Cp′}](L2 = (PPh3)2, Cp′ = Cp; L2 = dppe, Cp′ = Cp*) in which the metal centres are bridged by an oligomeric phenylene ethynylene (OPE) ligand have been prepared and the electronic structure o... Read More about The electronic structures of diruthenium complexes containing an oligo(phenylene ethynylene) bridging ligand, and some related molecular structures.

Deboronation and Deprotonation of ortho-Carborane with N-Heterocyclic Carbenes (2010)
Journal Article
Willans, C., Kilner, C., & Fox, M. (2010). Deboronation and Deprotonation of ortho-Carborane with N-Heterocyclic Carbenes. Chemistry - A European Journal, 16(35), 10644-10648. https://doi.org/10.1002/chem.201001730

It is a matter of size: N-Heterocyclic carbenes can remove a proton from ortho-carborane to form a two-cage anion or attack the electropositive boron of ortho-carborane to yield a stable 1:2 carborane–carbene adduct. Which end product is formed depen... Read More about Deboronation and Deprotonation of ortho-Carborane with N-Heterocyclic Carbenes.

Luminescent Platinum(II) Complexes Containing Cyclometallated Diaryl Ketimine Ligands: Synthesis, Photophysical and Computational Properties (2010)
Journal Article
Pandya, S., Moss, K., Bryce, M., Batsanov, A., Fox, M., Jankus, V., …Monkman, A. (2010). Luminescent Platinum(II) Complexes Containing Cyclometallated Diaryl Ketimine Ligands: Synthesis, Photophysical and Computational Properties. European Journal of Inorganic Chemistry, 2010(13), 1963-1972. https://doi.org/10.1002/ejic.200901159

A new series of platinum(II) complexes containing cyclometallated diaryl ketimine ligands has been synthesised. The route involves reaction of diaryl ketimines with K[PtCl3(dmso)] to obtain trans-[PtCl2(imine)(dmso)] species, which underwent cyclomet... Read More about Luminescent Platinum(II) Complexes Containing Cyclometallated Diaryl Ketimine Ligands: Synthesis, Photophysical and Computational Properties.

Some reactions of an eta(3)-tetracyanobutadienyl-ruthenium complex (2010)
Journal Article
Bruce, M. I., Fox, M. A., Low, P. J., Skelton, B. W., & Zaitseva, N. N. (2010). Some reactions of an eta(3)-tetracyanobutadienyl-ruthenium complex. Dalton Transactions, 39(15), 3759-3770. https://doi.org/10.1039/b921324d

In the η3-butadienyl complex Ru{η3-C(CN)2CPhC[double bond, length as m-dash]C(CN)2}(PPh3)Cp 1, which is formed from Ru(C[triple bond, length as m-dash]CPh)(PPh3)2Cp and tcne, a CN group reacts with MeO− to give the methoxy-amide Ru{NH[double bond, le... Read More about Some reactions of an eta(3)-tetracyanobutadienyl-ruthenium complex.

Syntheses and molecular structures of some tricobalt carbonyl clusters containing 2,4,6-trimethyl-1,3,5-trithiane (2010)
Journal Article
Bruce, M., Zaitseva, N., Skelton, B., White, A., Fox, M., & Low, P. (2010). Syntheses and molecular structures of some tricobalt carbonyl clusters containing 2,4,6-trimethyl-1,3,5-trithiane. Dalton Transactions, 39(5), 1222-1234. https://doi.org/10.1039/b909708b

Reactions of CCo3 carbonyl clusters Co3(μ3-CR)(CO)9 with 2,4,6-trimethyl-1,3,5-trithiane (SMe3) have given Co3(μ3-CR)(μ3-SMe3)(CO)6 [R = H (1), CCSiMe3 (2)]. A small amount of the coupled-alkyne product Me3SiC2[Co2(CO)6]C2[Co2(μ-SMe3)(CO)4]CCSiMe3 (3... Read More about Syntheses and molecular structures of some tricobalt carbonyl clusters containing 2,4,6-trimethyl-1,3,5-trithiane.

Tuning the Intramolecular Charge Transfer Emission from Deep Blue to Green in Ambipolar Systems Based On Dibenzothiophene S S-Dioxide by Manipulation of Conjugation and Strength of the Electron Donor Units (2010)
Journal Article
Moss, K., Bourdakos, K., Bhalla, V., Kamtekar, K., Bryce, M., Fox, M., …Monkman, A. (2010). Tuning the Intramolecular Charge Transfer Emission from Deep Blue to Green in Ambipolar Systems Based On Dibenzothiophene S S-Dioxide by Manipulation of Conjugation and Strength of the Electron Donor Units. Journal of Organic Chemistry, 75(20), 6771-6781. https://doi.org/10.1021/jo100898a

The efficient synthesis and photophysical properties of a series of ambipolar donor−acceptor−donor systems is described where the acceptor is dibenzothiophene S,S-dioxide and the donor is fluorene, carbazole, or arylamine. The systems exhibit intramo... Read More about Tuning the Intramolecular Charge Transfer Emission from Deep Blue to Green in Ambipolar Systems Based On Dibenzothiophene S S-Dioxide by Manipulation of Conjugation and Strength of the Electron Donor Units.