Outputs (6)

Rigidly linked dinuclear platinum( ii ) complexes showing intense, excimer-like, near-infrared luminescence (2023)
Journal Article
Pander, P., Walden, M. T., Salthouse, R. J., Sil, A., Yufit, D. S., Dias, F. B., & Williams, J. A. G. (2023). Rigidly linked dinuclear platinum( ii ) complexes showing intense, excimer-like, near-infrared luminescence. Journal of Materials Chemistry C Materials for optical and electronic devices, 11(43), 15335-15346. https://doi.org/10.1039/d3tc03432a

Many luminescent platinum(ii) complexes undergo face-to-face interactions between neighbouring molecules, leading to bimolecular excited states that may emit at lower energy (dimers and/or excimers). Detailed photophysical studies are reported on din... Read More about Rigidly linked dinuclear platinum( ii ) complexes showing intense, excimer-like, near-infrared luminescence.

Cyclometallated Platinum(II) Complexes Featuring an Unusual, C^N‐Coordinating Pyridyl‐pyridylidene Ligand and L X Coligands: Synthesis, Structures and Dual Luminescence Behavior (2023)
Journal Article
Montagu, J., Gontard, G., Williams, J. A. G., & Moussa, J. (2023). Cyclometallated Platinum(II) Complexes Featuring an Unusual, C^N‐Coordinating Pyridyl‐pyridylidene Ligand and L X Coligands: Synthesis, Structures and Dual Luminescence Behavior. European Journal of Inorganic Chemistry, 26(32), Article e202300487. https://doi.org/10.1002/ejic.202300487

Thanks to an unusual protodemethylation reaction, a series of luminescent cyclometallated platinum(II) complexes can be prepared, which incorporate a rare NC-chelating, pyridyl-pyridylidene ligand, in combination with OO-coordinating acetylacetonate... Read More about Cyclometallated Platinum(II) Complexes Featuring an Unusual, C^N‐Coordinating Pyridyl‐pyridylidene Ligand and L X Coligands: Synthesis, Structures and Dual Luminescence Behavior.

Platinum(II) Complexes of Nonsymmetrical NCN-Coordinating Ligands: Unimolecular and Excimeric Luminescence Properties and Comparison with Symmetrical Analogues (2023)
Journal Article
Salthouse, R. J., Sil, A., Gildea, L. F., Yufit, D. S., & Williams, J. A. G. (2023). Platinum(II) Complexes of Nonsymmetrical NCN-Coordinating Ligands: Unimolecular and Excimeric Luminescence Properties and Comparison with Symmetrical Analogues. Inorganic Chemistry, 62(31), 12356-12371. https://doi.org/10.1021/acs.inorgchem.3c01439

A series of seven new platinum(II) complexes PtLnCl have been prepared, where Ln is an NCN-coordinating ligand comprising a benzene ring 1,3-disubstituted with two different azaheterocycles. In PtL1–5Cl, one heterocycle is a simple pyridine ring, whi... Read More about Platinum(II) Complexes of Nonsymmetrical NCN-Coordinating Ligands: Unimolecular and Excimeric Luminescence Properties and Comparison with Symmetrical Analogues.

Enantiopure cycloplatinated pentahelicenic N-heterocyclic carbenic complexes that display long-lived circularly polarized phosphorescence (2023)
Journal Article
Kundu, D., del Rio, N., Cordier, M., Vanthuyne, N., Puttock, E. V., Meskers, S. C. J., …Crassous, J. (2023). Enantiopure cycloplatinated pentahelicenic N-heterocyclic carbenic complexes that display long-lived circularly polarized phosphorescence. Dalton Transactions, 52(19), 6484-6493. https://doi.org/10.1039/d3dt00577a

The preparation of the first enantiopure cycloplatinated complexes bearing a bidentate, helicenic N-heterocyclic carbene and a diketonate ancillary ligand is presented, along with their structural and spectroscopic characterization based on both expe... Read More about Enantiopure cycloplatinated pentahelicenic N-heterocyclic carbenic complexes that display long-lived circularly polarized phosphorescence.

Modulation of chiroptical and photophysical properties in helicenic rhenium(I) systems: the use of an N‐(aza[6]helicenyl)‐NHC ligand (2023)
Journal Article

The photophysical and chiroptical properties of a novel, chiral helicene-NHC−Re(I) complex bearing an N-(aza[6]helicenyl)-benzimidazolylidene ligand are described, showing its ability to emit yellow circularly polarized luminescence. A comparative an... Read More about Modulation of chiroptical and photophysical properties in helicenic rhenium(I) systems: the use of an N‐(aza[6]helicenyl)‐NHC ligand.

Platinum(IV) Complexes with Tridentate, NNC-Coordinating Ligands: Synthesis, Structures, and Luminescence (2023)
Journal Article

Platinum(II) complexes of NNC-cyclometalating ligands based on 6-phenyl-2,2′-bipyridine (HL1) have been widely investigated for their luminescence properties. We describe how PtL1Cl and five analogues with differently substituted aryl rings, PtL2–6Cl... Read More about Platinum(IV) Complexes with Tridentate, NNC-Coordinating Ligands: Synthesis, Structures, and Luminescence.