Effects of ortho- and para-ring activation on the kinetics of S<sub>N</sub>Ar reactions of 1-chloro-2-nitro and 1-phenoxy-2-nitrobenzenes with aliphatic amines in acetonitrile
(2005)
Journal Article
Crampton, M., Emokpae, T., Isanbor, C., Batsanov, A., Howard, J., & Mondal, R. (2006). Effects of ortho- and para-ring activation on the kinetics of SNAr reactions of 1-chloro-2-nitro and 1-phenoxy-2-nitrobenzenes with aliphatic amines in acetonitrile. European Journal of Organic Chemistry, 2006(5), 1222-1230. https://doi.org/10.1002/ejoc.200500774
Rate constants are reported for reaction of 4-substituted 1-chloro-2,6-dinitrobenzenes 1, 6-substituted 1-chloro-2,4-dinitrobenzenes 2, and some of the corresponding 1-phenoxy derivatives, 3 and 4, with n-butylamine, pyrrolidine and piperidine in ace... Read More about Effects of ortho- and para-ring activation on the kinetics of S<sub>N</sub>Ar reactions of 1-chloro-2-nitro and 1-phenoxy-2-nitrobenzenes with aliphatic amines in acetonitrile.