Platinum catalysed 3,4- and 1,4-diboration of alpha,beta-unsaturated carbonyl compounds using bis-pinacolatodiboron
Journal Article
Bell, N., Cox, A., Cameron, N., Evans, J., Marder, T., Duin, M., Elsevier, C., Baucherel, X., Tulloch, A., & Tooze, R. (online). Platinum catalysed 3,4- and 1,4-diboration of alpha,beta-unsaturated carbonyl compounds using bis-pinacolatodiboron. Chemical Communications, 1854-1855
Bis-pinacolatodiboron reacts with alpha,beta-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.