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Fluorescence and Phosphorescence Anisotropy from Oriented Films of Thermally Activated Delayed Fluorescence Emitters (2017)
Journal Article
Higginbotham, H. F., Etherington, M. K., & Monkman, A. P. (2017). Fluorescence and Phosphorescence Anisotropy from Oriented Films of Thermally Activated Delayed Fluorescence Emitters. Journal of Physical Chemistry Letters, https://doi.org/10.1021/acs.jpclett.7b00729

Anisotropy within three TADF materials has been observed using steady-state fluorescence polarisation. This technique has allowed for the observation of differences in polarisation within dilute solution, and both un-stretched and stretched films; th... Read More about Fluorescence and Phosphorescence Anisotropy from Oriented Films of Thermally Activated Delayed Fluorescence Emitters.

Revealing the spin–vibronic coupling mechanism of thermally activated delayed fluorescence (2016)
Journal Article
Etherington, M. K., Gibson, J., Higginbotham, H. F., Penfold, T. J., & Monkman, A. P. (2016). Revealing the spin–vibronic coupling mechanism of thermally activated delayed fluorescence. Nature Communications, 7, Article 13680. https://doi.org/10.1038/ncomms13680

Knowing the underlying photophysics of thermally activated delayed fluorescence (TADF) allows proper design of high efficiency organic light-emitting diodes. We have proposed a model to describe reverse intersystem crossing (rISC) in donor–acceptor c... Read More about Revealing the spin–vibronic coupling mechanism of thermally activated delayed fluorescence.