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Enhanced Carrier Collection in Cd/In-Based Dual Buffers in Kesterite Thin-Film Solar Cells from Nanoparticle Inks

Campbell, Stephen; Zoppi, Guillaume; Bowen, Leon; Maiello, Pietro; Barrioz, Vincent; Beattie, Neil S.; Qu, Yongtao

Enhanced Carrier Collection in Cd/In-Based Dual Buffers in Kesterite Thin-Film Solar Cells from Nanoparticle Inks Thumbnail


Authors

Stephen Campbell

Guillaume Zoppi

Leon Bowen leon.bowen@durham.ac.uk
Senior Manager (Electron Microscopy)

Pietro Maiello

Vincent Barrioz

Neil S. Beattie

Yongtao Qu



Abstract

Increasing the power conversion efficiency (PCE) of kesterite Cu2ZnSn­(S,Se)4 (CZTSSe) solar cells has remained challenging over the past decade, in part due to open-circuit voltage (V OC)-limiting defect states at the absorber/buffer interface. Previously, we found that substituting the conventional CdS buffer layer with In2S3 in CZTSSe devices fabricated from nanoparticle inks produced an increase in the apparent doping density of the CZTSSe film and a higher built-in voltage arising from a more favorable energy-band alignment at the absorber/buffer interface. However, any associated gain in V OC was negated by the introduction of photoactive defects at the interface. This present study incorporates a hybrid Cd/In dual buffer in CZTSSe devices that demonstrate an average relative increase of 11.5% in PCE compared to CZTSSe devices with a standard CdS buffer. Current density–voltage analysis using a double-diode model revealed the presence of (i) a large recombination current in the quasi-neutral region (QNR) of the CZTSSe absorber in the standard CdS-based device, (ii) a large recombination current in the space-charge region (SCR) of the hybrid buffer CZTSSe–In2S3–CdS device, and (iii) reduced recombination currents in both the QNR and SCR of the CZTSSe–CdS–In2S3 device. This accounts for a notable 9.0% average increase in the short-circuit current density (J SC) observed in CZTSSe–CdS–In2S3 in comparison to the CdS-only CZTSSe solar cells. Energy-dispersive X-ray, secondary-ion mass spectroscopy, and grazing-incidence X-ray diffraction compositional analysis of the CZTSSe layer in the three types of kesterite solar cells suggest that there is diffusion of elemental In and Cd into the absorbers with a hybrid buffer. Enhanced Cd diffusion concomitant with a double postdeposition heat treatment of the hybrid buffer layers in the CZTSSe–CdS–In2S3 device increases carrier collection and extraction and boosts J SC. This is evidenced by electron-beam-induced current measurements, where higher current generation and collection near to the p–n junction is observed, accounting for the increase in J SC in this device. It is expected that optimization of the heat treatment of the hybrid buffer layers will lead to further improvements in the device performance.

Citation

Campbell, S., Zoppi, G., Bowen, L., Maiello, P., Barrioz, V., Beattie, N. S., & Qu, Y. (2023). Enhanced Carrier Collection in Cd/In-Based Dual Buffers in Kesterite Thin-Film Solar Cells from Nanoparticle Inks. ACS Applied Energy Materials, 6(21), 10883-10896. https://doi.org/10.1021/acsaem.3c01622

Journal Article Type Article
Acceptance Date Oct 5, 2023
Online Publication Date Oct 27, 2023
Publication Date Nov 13, 2023
Deposit Date Dec 20, 2023
Publicly Available Date Dec 20, 2023
Journal ACS Applied Energy Materials
Print ISSN 2574-0962
Electronic ISSN 2574-0962
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 6
Issue 21
Pages 10883-10896
DOI https://doi.org/10.1021/acsaem.3c01622
Keywords CZTSSe, In2S3−CdS buffer, EBIC, kesterite, nanoparticle inks
Public URL https://durham-repository.worktribe.com/output/1932470

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