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Unexpected temperature, time and solvent effects in the catalytic asymmetric aza-Diels-Alder reaction of an ethyl glyoxylate-derived N-aryl imine with Danishefsky's diene catalysed by a BINOL-zinc complex

Guillarme, S.; Whiting, A.

Authors

S. Guillarme



Abstract

The catalytic asymmetric aza-Diels-Alder reaction of an ethyl glyoxylate-derived N-aryl imine with Danishefsky's diene using a BINOL-zinc complex provides the corresponding cycloadduct with moderate to high enantioselectivity, depending on the solvent, temperature and reaction time.

Citation

Guillarme, S., & Whiting, A. (online). Unexpected temperature, time and solvent effects in the catalytic asymmetric aza-Diels-Alder reaction of an ethyl glyoxylate-derived N-aryl imine with Danishefsky's diene catalysed by a BINOL-zinc complex. Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, 711-713

Journal Article Type Article
Journal Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry
Print ISSN 0936-5214
Electronic ISSN 1437-2096
Publisher Thieme Gruppe
Peer Reviewed Peer Reviewed
Issue 4
Pages 711-713
Public URL https://durham-repository.worktribe.com/output/1602334