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Synthesis and luminescence properties of dinuclear lanthanide complexes derived from covalently linked macrocyclic ligands

Pope, S.J.A.; Kenwright, A.M.; Boote, V.A.; Faulkner, S.

Authors

S.J.A. Pope

A.M. Kenwright

V.A. Boote

S. Faulkner



Abstract

A series of homo-binuclear lanthanide complexes have been prepared from DO3A derived systems containing seven-coordinate binding domains linked via an aromatic. The luminescence properties of xylyl bridged complexes show that the lanthanide ions behave as isolated centres, while the combination of the lanthanide contraction and the lipophilicity of the linker group limits inner-sphere hydration around the metal centres for later lanthanides such as ytterbium.

Citation

Pope, S., Kenwright, A., Boote, V., & Faulkner, S. (2003). Synthesis and luminescence properties of dinuclear lanthanide complexes derived from covalently linked macrocyclic ligands. Dalton Transactions, 3780-3784

Journal Article Type Article
Publication Date 2003
Journal Dalton Transactions
Print ISSN 1477-9226
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Issue 19
Pages 3780-3784
Public URL https://durham-repository.worktribe.com/output/1601139