Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II)

Tuxworth, Luke; Baiget, Lise; Phanopoulos, Andreas; Metters, Owen J.; Batsanov, Andrei S.; Fox, Mark A.; Howard, Judith A.K.; Dyer, Philip W.

Abstract

N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine–alkene ligand for Pd0 and PdII, promoting direct alkyl–alkyl and indirect alkyl–halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine–alkene)Pd0 complex.

Citation

Tuxworth, L., Baiget, L., Phanopoulos, A., Metters, O. J., Batsanov, A. S., Fox, M. A., …Dyer, P. W. (2012). Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II). Chemical Communications, 48(84), 10413-10415. https://doi.org/10.1039/c2cc35623f

• Journal Article Type: Article
• Publication Date: Sep 26, 2012
• Deposit Date: May 2, 2013
• Publicly Available Date: Jul 18, 2014
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 48
• Issue: 84
• Pages: 10413-10415
• DOI: https://doi.org/10.1039/c2cc35623f