Dynamic behaviour in nicotinate-bridged binuclear ruthenium(IV) complexes

Steed, Jonathan W.; Tocher, Derek A.

Abstract

The isonicotinic acid adduct [Ru(η3:η3-C10H16)Cl2(p-NC5H4CO2H)] 1 and nicotinate and isonicotinate bridged binuclear complexes [Ru2(η3:η3-C10H16)2Cl3(μ-κN,O,O′-NC5H4CO2)] 2 and 3 are reported. Complexes 2 and 3 exist as mixtures of diastereoisomers and are dynamic in water saturated chloroform solution with complexes involving bidentate chelating carboxylate ligands in equilibrium with unidente carboxylate aquo complexes [Ru2(η3:η3-C10H16)2Cl3(OH2)(μ-κN,O-NC5H4CO2)].

Citation

Steed, J. W., & Tocher, D. A. (2018). Dynamic behaviour in nicotinate-bridged binuclear ruthenium(IV) complexes. Polyhedron, 147, 152-155. https://doi.org/10.1016/j.poly.2018.03.025

• Journal Article Type: Article
• Acceptance Date: Mar 25, 2018
• Online Publication Date: Apr 3, 2018
• Publication Date: Jun 1, 2018
• Deposit Date: Jun 8, 2018
• Publicly Available Date: Apr 3, 2019
• Journal: Polyhedron
• Print ISSN: 0277-5387
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 147
• Pages: 152-155
• DOI: https://doi.org/10.1016/j.poly.2018.03.025