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Unravelling the Complexities of Pseudocontact Shift Analysis in Lanthanide Coordination Complexes of Differing Symmetry

Parker, David; Suturina, Elizaveta; Harnden, Alice; Batsanov, Andrei; Fox, Mark; Mason, Kevin; Vonci, Michele; McInnes, Eric; Chilton, Nicholas

Unravelling the Complexities of Pseudocontact Shift Analysis in Lanthanide Coordination Complexes of Differing Symmetry Thumbnail


Authors

Elizaveta Suturina

Alice Harnden

Kevin Mason

Michele Vonci

Eric McInnes

Nicholas Chilton



Abstract

In two closely related series of eight‐coordinate lanthanide complexes, a switch in the sign of the dominant ligand field parameter and striking variations in the sign, amplitude and orientation of the main component of the magnetic susceptibility tensor as the Ln3+ ion is permuted conspire to mask modest changes in NMR paramagnetic shifts, but are evident in Yb EPR and Eu emission spectra.

Citation

Parker, D., Suturina, E., Harnden, A., Batsanov, A., Fox, M., Mason, K., …Chilton, N. (2019). Unravelling the Complexities of Pseudocontact Shift Analysis in Lanthanide Coordination Complexes of Differing Symmetry. Angewandte Chemie, 131(30), 10936-10400. https://doi.org/10.1002/anie.201906031

Journal Article Type Article
Acceptance Date May 28, 2019
Online Publication Date May 29, 2019
Publication Date Jul 31, 2019
Deposit Date May 30, 2019
Publicly Available Date May 29, 2020
Journal Angewandte Chemie
Print ISSN 0044-8249
Electronic ISSN 1521-3757
Publisher Wiley
Peer Reviewed Peer Reviewed
Volume 131
Issue 30
Pages 10936-10400
DOI https://doi.org/10.1002/anie.201906031

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Copyright Statement
This is the accepted version of the following article: Parker, David, Suturina, Elizaveta, Harnden, Alice, Batsanov, Andrei, Fox, Mark, Mason, Kevin, Vonci, Michele, McInnes, Eric & Chilton, Nicholas (2019). Unravelling the Complexities of Pseudocontact Shift Analysis in Lanthanide Coordination Complexes of Differing Symmetry. Angewandte Chemie 131(30): 10396-10400., which has been published in final form at https://doi.org/10.1002/anie.201906031. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for self-archiving.







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