Benjamin François
Access to Fused Pyrroles from Cyclic 1,3-Dienyl Boronic Esters and Arylnitroso Compounds
François, Benjamin; Eberlin, Ludovic; Berrée, Fabienne; Whiting, Andrew; Carboni, Bertrand
Authors
Ludovic Eberlin
Fabienne Berrée
Professor Andrew Whiting andy.whiting@durham.ac.uk
Professor
Bertrand Carboni
Abstract
Complimentary to classical hydroboration and boron-Wittig reactions, a new, efficient access to cyclic 1,3-dienyl boronic esters has been developed via diene or triene metathesis. Subsequently, fused pyrroles were synthesized with a broad substrate scope from the reaction of cyclic 1,3-dienyl boronic esters with arylnitroso compounds using a one-pot hetero-Diels−Alder/ring contraction sequence.
Citation
François, B., Eberlin, L., Berrée, F., Whiting, A., & Carboni, B. (2020). Access to Fused Pyrroles from Cyclic 1,3-Dienyl Boronic Esters and Arylnitroso Compounds. Journal of Organic Chemistry, 85(8), 5173-5182. https://doi.org/10.1021/acs.joc.9b03214
| Journal Article Type | Article |
|---|---|
| Online Publication Date | Mar 20, 2020 |
| Publication Date | Apr 17, 2020 |
| Deposit Date | Mar 24, 2020 |
| Publicly Available Date | Mar 20, 2021 |
| Journal | Journal of Organic Chemistry |
| Print ISSN | 0022-3263 |
| Electronic ISSN | 1520-6904 |
| Publisher | American Chemical Society |
| Peer Reviewed | Peer Reviewed |
| Volume | 85 |
| Issue | 8 |
| Pages | 5173-5182 |
| DOI | https://doi.org/10.1021/acs.joc.9b03214 |
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Accepted Journal Article
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Copyright Statement
This document is the Accepted Manuscript version of a Published Work that appeared in final form in the Journal of organic chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.9b03214